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Piezoelectric ceramics have non-centrosymmetric unit cells below the Curie temperature and centrosymmetric unit cells above the Curie temperature. Non-centrosymmetric structures provide a net electric dipole moment. The dipoles are randomly oriented until a strong DC electric field is applied causing permanent polarization and thus piezoelectric properties.
A polarized ceramic may be subjected to stress causing the crystal lattice to distort changing the total dipole moment of the ceramic. The change in dipole moment due to an applied stress causes a net electric field which varies linearly with stress.