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The Dutch and the Germans were the great brickmakers of Europe during the middle ages, although the Italians, from the 14th to the 15th century, revived and developed the art of decorative brick-work or terra-cotta, and discovered the method of applying coloured enamels to these materials. Under the Della Robbias, in the 15th century, some of the finest work of this class that the world has seen was executed, but it can scarcely be included under brickwork.
Brick Clays.?All clays are the result of the denudation and decomposition of felspathic and siliceous rocks, and consist of the fine insoluble particles which have been carried in suspension in water and deposited in geologic basins according to their specific gravity and degree of fineness (see Clay). These deposits have been formed in all geologic epochs from the "Recent" to the "Cambrian," and they vary in hardness from the soft and plastic "alluvial" clays to the hard and rock-like shales and slates of the older formations. The alluvial and drift clays (which were alone used for brickmaking until modern times) are found near the surface, are readily worked and require little preparation, whereas the older sedimentary deposits are often difficult to work and necessitate the use of heavy machinery. These older shales, or rocky clays, may be brought into plastic condition by long weathering (i.e. by exposure to rain, frost and sun) or by crushing and grinding in water, and they then resemble ordinary alluvial clays in every respect.
The clays or earths from which burnt bricks are made may be divided into two principal types, according to chemical composition: (1) Clays or shales containing only a small percentage of carbonate of lime and consisting chiefly of hydrated aluminium silicates (the "true clay substance") with more or less sand, undecomposed grains of felspar, and oxide or carbonate of iron; these clays usually burn to a buff, salmon or red colour; (2) Clays containing a considerable percentage of carbonate of lime in addition to the substances above mentioned. These latter clay deposits are known as "marls,"[1] and may contain as much as 40% of chalk. They burn to a sulphur-yellow colour which is quite distinctive.
Brick clays of class (1) are very widely distributed, and have a more extensive geological range than the marls, which are found in connexion with chalk or limestone formations only. These ordinary brick clays vary considerably in composition, and many clays, as they are found in nature, are unsuitable for brickmaking without the addition of some other kind of clay or sand. The strongest brick clays, i.e. those possessing the greatest plasticity and tensile strength, are usually those which contain the highest percentage of the hydrated aluminium silicates, although the exact relation of plasticity to chemical composition has not yet been determined. This statement cannot be applied indiscriminately to all clays, but may be taken as fairly applicable to clays of one general type (see Clay). All clays contain more or less free silica in the form of sand, and usually a small percentage of undecomposed felspar. The most important ingredient, after the clay-substance and the sand, is oxide of iron; for the colour, and, to a less extent, the hardness and durability of the burnt bricks depend on its presence. The amount of oxide of iron in these clays varies from about 2 to 10%, and the colour of the bricks varies accordingly from light buff to chocolate; although the colour developed by a given percentage of oxide of iron is influenced by the other substances present and also by the method of firing. A clay containing from 5 to 8% of oxide of iron will, under ordinary conditions of firing, produce a red brick; but if the clay contains 3 to 4% of alkalis, or the brick is fired too hard, the colour will be darker and more purple. The actions of the alkalis and of increased temperature are probably closely related, for in either case the clay is brought nearer to its fusion point, and ferruginous clays generally become darker in colour as they approach to fusion. Alumina acts in the opposite direction, an excess of this compound tending to make the colour lighter and brighter. It is impossible to give a typical composition for such clays, as the percentages of the different constituents vary through