such wide ranges. The clay substance may vary from 15 to 80%, the free silica or sand from 5 to 80%, the oxide of iron from 1 to 10%, the carbonates of lime and magnesia together, from 1 to 5%, and the alkalis from 1 to 4%. Organic matter is always present, and other impurities which frequently occur are the sulphates of lime and magnesia, the chlorides and nitrates of soda and potash, and iron-pyrites. The presence of organic matter gives the wet clay a greater plasticity, probably because it forms a kind of mucilage which adds a certain viscosity and adhesiveness to the natural plasticity of the clay. In some of the coal-measure shales the amount of organic matter is very considerable, and may render the clay useless for brickmaking. The other impurities, all of which, except the pyrites, are soluble in water, are undesirable, as they give rise to "scum," which produces patchy colour and pitted faces on the bricks. The commonest soluble impurity is calcium sulphate, which produces a whitish scum on the face of the brick in drying, and as the scum becomes permanently fixed in burning, such bricks are of little use except for common work. This question of "scumming" is very important to the maker of high-class facing and moulded bricks, and where a clay containing calcium sulphate must be used, a certain percentage of barium carbonate is nowadays added to the wet clay. By this means the calcium sulphate is converted into calcium carbonate which is insoluble in water, so that it remains distributed throughout the mass of the brick instead of being deposited on the surface. The presence of magnesium salts is also very objectionable, as these generally remain in the burnt brick as magnesium sulphate, which gives rise to an efflorescence of fine white crystals after the bricks are built into position. Clays which are strong or plastic are known as "fat" clays, and they always contain a high percentage of true "clay substance," and, consequently, a low percentage of sand. Such clays take up a considerable amount of water in "tempering"; they dry slowly, shrink greatly, and so become liable to lose their shape and develop cracks in drying and firing. "Fat" clays are greatly improved by the addition of coarse sharp sand,
which reduces the time of drying and the shrinkage, and makes the brick more rigid during the firing. Coarse sand, unlike clay-substance, is practically unaffected during the drying and firing, and is a desirable if not a necessary ingredient of all brick clays. The best brick-clays feel gritty between the fingers; they should, of course, be free from pebbles, sufficiently plastic to be moulded into shape and strong enough when dry to be safely handled. All clays are greatly improved by being turned over and exposed to the weather, or by standing for some months in a wet condition. This "weathering" and "ageing" of clay is particularly important where bricks are made from tempered clay,
i.e. clay in the wet or plastic state; where bricks are made from shale, in the semi-plastic condition, weathering is still of importance.
The lime clays or "marls" of class (2), which contain essentially a high percentage of chalk or limestone, are not so widely distributed as the ordinary brick-clays, and in England the natural deposits of these clays have been largely exhausted. A very fine chalk-clay, or "malm" as it was locally called, was formerly obtained from the alluvium in the vicinity of London; but the available supply of this has been used up, and at the present time an artificial "malm" is prepared by mixing an ordinary brick-clay with ground chalk. For the best London facing-bricks the clay and chalk are mixed in water. The chalk is ground on grinding-pans, and the clay is mixed with water and worked about until the mixture has the consistence of cream. The mixture of these "pulps" is run through a grating or coarse sieve on to a drying-kiln or "bed," where it is allowed to stand until stiff enough to walk on. A layer of fine ashes is then spread over the clay, and the mass is turned over and mixed by spade, and tempered by the addition of water. In other districts, where clays containing limestone are used, the marl is mixed with water on a wash-pan and the resulting creamy fluid passed through coarse sieves on to a drying-bed. If necessary, coarse sand is added to the clay in the wash-pan, and such addition is often advisable because the washed clays are generally very fine in grain. Another method of treating these marls, when they are in the plastic condition, is to squeeze them by machinery through iron gratings, which arrest and remove the pebbles. In other cases the marl is passed through a grinding-mill having a solid bottom and heavy iron rollers, by which means the limestone pebbles are crushed sufficiently and mixed through the whole mass. The removal of limestone pebbles from the clay is of great
